The continuous advancement of the VUCA era has led to an increasing number of challenges faced by enterprises, further strengthening the rule of “innovation is king” and forcing enterprises to continuously innovate to shape their ability to respond to changes. As the basic unit of enterprises, employees’ creativity directly determines the creativity of their respective enterprises. Due to the fact that innovative activities are the result of social processes, other people in the workplace, such as leaders, can have a certain impact on employee creativity. However, the existing research on the impact mechanism of leadership creativity on employee creativity is not yet sound. Based on this, the impact mechanism of leadership creativity on employee creativity from the perspective of social learning theory was explored. On the basis of the empirical research through 301 questionnaire surveys, it is found that leadership creativity can positively influence employee creativity through dual learning. Proactive personality positively moderates the positive effect of leadership creativity on employee creativity through dual learning.