Abstract:Uncertainty of e-commerce multiple demands, permeability of industrial boundaries, difference of supply chain synergies, and integration of rapid supply chain reconstruction give a lot of resistance to the development of B2C electronic commerce. This article briefly introduces relation of B2C e-commerce and multi logistics distribution. It compares domestic postal delivery mode, logistics alliance mode, third party logistics distribution mode and self-supporting logistics distribution mode. It puts forward development suggestions for B2C e-commerce supply chain.